+++Поиск 2-х соединений

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Уважаемые коллеги, помогите пожалуйста найти методы синтеза следующих соединений (Ar - любой ароматический заместитель)

1.

[Ar]C2([CN])CCN(Cc1ccccc1)CC2 JME 2006.05 Sun May 20 20:13:06 GMT+04:00 2012 15 16 0 0 0 0 0 0 0 0999 V2000 0.0000 0.1469 0.0000 Ar 0 0 0 0 0 0 0 0 0 0 0 0 2.5083 0.0000 0.0000 CN 0 0 0 0 0 0 0 0 0 0 0 0 4.9276 6.9902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7152 7.6902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.9276 5.5902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 6.9902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7152 4.8902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0779 2.7902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 2.7902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0779 1.3902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 1.3902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2903 4.8902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 5.5902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2903 3.4902 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 1.2903 0.6902 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 15 1 0 0 0 0 2 15 1 0 0 0 0 3 4 1 0 0 0 0 3 5 2 0 0 0 0 4 6 2 0 0 0 0 5 7 1 0 0 0 0 6 13 1 0 0 0 0 7 13 2 0 0 0 0 8 10 1 0 0 0 0 8 14 1 0 0 0 0 9 11 1 0 0 0 0 9 14 1 0 0 0 0 10 15 1 0 0 0 0 11 15 1 0 0 0 0 12 13 1 0 0 0 0 12 14 1 0 0 0 0 M END

2.

NCC2([Ar])CCN(Cc1ccccc1)CC2 JME 2006.05 Sun May 20 20:13:37 GMT+04:00 2012 16 17 0 0 0 0 0 0 0 0999 V2000 2.5027 0.0000 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 1.5567 0.0000 Ar 0 0 0 0 0 0 0 0 0 0 0 0 4.9276 8.4000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.9276 7.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7152 9.1000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7152 6.3000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 8.4000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 1.4000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 4.2000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0779 4.2000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 2.8000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0779 2.8000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2903 6.3000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5027 7.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.2903 4.9000 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 1.2903 2.1000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1 8 1 0 0 0 0 2 16 1 0 0 0 0 3 4 2 0 0 0 0 3 5 1 0 0 0 0 4 6 1 0 0 0 0 5 7 2 0 0 0 0 6 14 2 0 0 0 0 7 14 1 0 0 0 0 8 16 1 0 0 0 0 9 11 1 0 0 0 0 9 15 1 0 0 0 0 10 12 1 0 0 0 0 10 15 1 0 0 0 0 11 16 1 0 0 0 0 12 16 1 0 0 0 0 13 14 1 0 0 0 0 13 15 1 0 0 0 0 M END

Заранее благодарю!!

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Reaxys

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Благодарю anonimous

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SF

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Спасибо Огромное SkydiVAR

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